@article{OschatzZeigerJaeckeletal.2015,
  author    = {Martin Oschatz and Marco Zeiger and Nicolas J{\"a}ckel and Patrick Strubel and Lars Borchardt and Romy Reinhold and Winfried Nickel and J{\"u}rgen Eckert and Volker Presser and Stefan Kaskel},
  title     = {Emulsion soft templating of carbide-derived carbon nanospheres with controllable porosity for capacitive electrochemical energy storage},
  series   = {Journal of Materials Chemistry A},
  volume    = {3},
  number    = {35},
  issn      = {2050-7488},
  doi       = {10.1039/c5ta03730a},
  url       = {https://nbn-resolving.org/urn:nbn:de:bsz:291:415-4124},
  pages     = {17983 -- 17990},
  year      = {2015},
  abstract  = {A new approach to produce carbide-derived carbon nanospheres of 20-200 nm in diameter based on a novel soft-templating technique is presented. Platinum catalysis is used for the cross-linking of liquid (allylhydrido)polycarbosilane polymer chains with para-divinylbenzene within oil-in-water miniemulsions. Quantitative implementation of the pre-ceramic polymer can be achieved allowing precise control over the resulting materials. After pyrolysis and high-temperature chlorine treatment, resulting particles offer ideal spherical shape, very high specific surface area (up to 2347 m 2 /g), and large micro/mesopore volume (up to 1.67 cm 3 /g). The internal pore structure of the nanospheres is controllable by the composition of the oil phase within the miniemulsions. The materials are highly suitable for electrochemical double-layer capacitors with high specific capacitances in aqueous 1 M Na 2 SO 4 solution (110 F/g) and organic 1 M tetraethylammonium tetrafluoroborate in acetonitrile (130 F/g).},
  language  = {en}
}