@article{VeithSummaAnneletal.2019,
  author    = {Veith, Michael and Summa, Daniela and Annel, Uwe and Huch, Volker},
  title     = {Gallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert-Butoxide as further Components},
  journal   = {Zeitschrift f{\"u}r anorganische und allgemeine Chemie},
  volume    = {645},
  number    = {22},
  issn      = {0044-2313},
  doi       = {10.1002/zaac.201900240},
  pages     = {1272 -- 1278},
  year      = {2019},
  abstract  = {Gallium hydride stabilized by the base quinonuclidine reacts with acetone under addition of the Ga-H function to the carbon-oxygen double bond yielding (HGa)5(OiPr)8O (1) as isolable compound. (HGa)5(OiPr)8O may be formally split in to four entities of HGa(OiPr)2 and one entity HGaO. The inner atomic skeleton of 1 is a novel Ga5O9 heterocluster with gallium atoms occupying the corners of a distorted trigonal bi-pyramid, an oxygen atom in the center and the remaining alcoholate oxygen atoms bridging eight of the nine edges of the bi-pyramid (X-ray diffraction analysis). Potassium indium alkoxide KIn(OtBu)4 has been used to synthesize several new compounds like In4(OtBu)8(C5H4)2 (2), (py)2CuIn(OtBu)4 (3), and [CuIn(OtBu)4]2 (4) by reaction with TiCl2cp2 (2) and CuCl (3, 4). All compounds were characterized by spectroscopic means and by X-ray structure analyses revealing novel polycyclic structures.},
  language  = {en}
}