TY  - JOUR
U1  - Wissenschaftlicher Artikel
A1  - Veith, Michael
A1  - Summa, Daniela
A1  - Annel, Uwe
A1  - Huch, Volker
T1  - Gallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert-Butoxide as further Components
JF  - Zeitschrift für anorganische und allgemeine Chemie
N2  - Gallium hydride stabilized by the base quinonuclidine reacts with acetone under addition of the Ga-H function to the carbon–oxygen double bond yielding (HGa)5(OiPr)8O (1) as isolable compound. (HGa)5(OiPr)8O may be formally split in to four entities of HGa(OiPr)2 and one entity HGaO. The inner atomic skeleton of 1 is a novel Ga5O9 heterocluster with gallium atoms occupying the corners of a distorted trigonal bi-pyramid, an oxygen atom in the center and the remaining alcoholate oxygen atoms bridging eight of the nine edges of the bi-pyramid (X-ray diffraction analysis). Potassium indium alkoxide KIn(OtBu)4 has been used to synthesize several new compounds like In4(OtBu)8(C5H4)2 (2), (py)2CuIn(OtBu)4 (3), and [CuIn(OtBu)4]2 (4) by reaction with TiCl2cp2 (2) and CuCl (3, 4). All compounds were characterized by spectroscopic means and by X-ray structure analyses revealing novel polycyclic structures.
Y1  - 2019
UN  - https://nbn-resolving.org/urn:nbn:de:bsz:291:415-4824
SN  - 0044-2313
SS  - 0044-2313
U6  - https://doi.org/10.1002/zaac.201900240
DO  - https://doi.org/10.1002/zaac.201900240
VL  - 645
IS  - 22
SP  - 1272
EP  - 1278
ER  -