TY - JOUR U1 - Wissenschaftlicher Artikel A1 - Xue, Longjian A1 - Sanz, Belén A1 - Luo, Aoyi A1 - Turner, Kevin T. A1 - Wang, Xin A1 - Tan, Di A1 - Zhang, Rui A1 - Du, Hang A1 - Steinhart, Martin A1 - Mijangos, Carmen A1 - Guttmann, Markus A1 - Kappl, Michael A1 - del Campo Bécares, Aránzazu T1 - Hybrid Surface Patterns Mimicking the Design of the Adhesive Toe Pad of Tree Frog JF - ACS Nano N2 - Biological materials achieve directional reinforcement with oriented assemblies of anisotropic building blocks. One such example is the nanocomposite structure of keratinized epithelium on the toe pad of tree frogs, in which hexagonal arrays of (soft) epithelial cells are crossed by densely packed and oriented (hard) keratin nanofibrils. Here, a method is established to fabricate arrays of tree-frog-inspired composite micropatterns composed of polydimethylsiloxane (PDMS) micropillars embedded with polystyrene (PS) nanopillars. Adhesive and frictional studies of these synthetic materials reveal a benefit of the hierarchical and anisotropic design for both adhesion and friction, in particular, at high matrix–fiber interfacial strengths. The presence of PS nanopillars alters the stress distribution at the contact interface of micropillars and therefore enhances the adhesion and friction of the composite micropattern. The results suggest a design principle for bioinspired structural adhesives, especially for wet environments. Y1 - 2017 UN - https://nbn-resolving.org/urn:nbn:de:bsz:291:415-4976 SN - 1936-0851 SS - 1936-0851 U6 - https://doi.org/10.1021/acsnano.7b04994 DO - https://doi.org/10.1021/acsnano.7b04994 VL - 11 IS - 10 SP - 9711 EP - 9719 ER -