TY  - JOUR
U1  - Wissenschaftlicher Artikel
A1  - Bornamehr, Behnoosh
A1  - Presser, Volker
A1  - Zarbin, Aldo J. G.
A1  - Yamauchi, Yusuke
A1  - Husmann, Samantha
T1  - Prussian blue and its analogues as functional template materials: control of derived structure compositions and morphologies
JF  - Journal of materials chemistry A
N2  - Hexacyanometallates, known as Prussian blue (PB) and its analogues (PBAs), are a class of coordination compounds with a regular and porous open structure. The PBAs are formed by the self-assembly of metallic species and cyanide groups. A uniform distribution of each element makes the PBAs robust templates to prepare hollow and highly porous (hetero)nanostructures of metal oxides, sulfides, carbides, nitrides, phosphides, and (N-doped) carbon, among other compositions. In this review, we examine methods to derive materials from PBAs focusing on the correlation between synthesis steps and derivative morphologies and composition. Insights into catalytic and electrochemical properties resulting from different derivatization strategies are also presented. We discuss challenges in manipulating the derivatives' properties, give perspectives of synthetic approaches for the target applications and present an outlook on less investigated grounds in Prussian blue derivatives.
Y1  - 2023
UN  - https://nbn-resolving.org/urn:nbn:de:bsz:291:415-6896
U6  - https://doi.org/10.1039/D2TA09501G
DO  - https://doi.org/10.1039/D2TA09501G
VL  - 11
SP  - 10473
EP  - 10492
ER  -