Volltext-Downloads (blau) und Frontdoor-Views (grau)

Acid-Base Interactions of Pyrazine, Ethyl Acetate, Di-alcohols, and Lysine with the cyclic Alumosiloxane (Ph2SiO)8[Al(O)OH]4 in View of Mimicking Al2O3(H2O) Surface Reactions

  • The etherate of (Ph2SiO)8[Al(O)OH]4 can be transformed into the pyrazine adduct (Ph2SiO)8[Al(O)OH]4·3N(C2H2)2N (1), the ethyl acetate adduct (Ph2SiO)8[Al(O)OH]4·3H3C-C(O)OC2H5 (2), the 1,6-hexane diol adduct (Ph2SiO)8[Al(O)OH]4·2HO–CH2(CH2)4CH2–OH (3) and the 1,4-cyclohexane diol adduct (Ph2SiO)8[Al(O)OH]4·4HO–CH(CH2CH2)2CH–OH (4). In all compounds the OH groups of the starting material bind to the bases through O–H···N (1) or O–H···O hydrogen bonds (2, 3, 4) as found from single-crystal X-ray diffraction analyses. Whereas in 1 only three of the central OH groups bind to the pyrazines, in 2 two of them bind to the same carbonyl oxygen atom of the ethyl acetate resulting in an unprecedented O–H···O···H–O double hydrogen bridge. The hexane diol adduct 3 in the crystal forms a one-dimensional coordination polymer with an intramolecularly to two OH groups grafted hexane diol loop, while the second hexane diol is connecting intermolecularly. In the cyclohexane diol adduct 4 all OH groups of the central Al4(OH)4 ring bind to different diols, leaving one alcohol group per diol uncoordinated. These “free” OH groups form an (O-H···)4 assembly creating a three-dimensional overall structure. When reacting with (Ph2SiO)8[Al(O)OH]4 lysine loses water, turns into the cyclic 3-amino-2-azepanone, and transforms through chelation of one of the aluminum atoms the starting material into a new polycycle. The isolated compound has the composition (Ph2SiO)12[Al(O)OH]4[Al2O3]2·4 C6H12N2O·6(CH2)4O (5).

Download full text files

Export metadata

Additional Services

Search Google Scholar


Document Type:Article
Author:Michael Veith, David Kolano, Volker HuchORCiD
Parent Title (English):Zeitschrift für anorganische und allgemeine Chemie
First Page:1846
Last Page:1853
Year of first Publication:2020
Release Date:2022/11/18
Impact:01.24 (2019)
Funding Information:Fonds der Chemischen Industrie
Open Access:Open Access
Signature:INM 2020/135
Licence (German):License LogoCreative Commons - CC BY-NC-ND - Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International