Heat-to-current conversion of low-grade heat from a thermocapacitive cycle by supercapacitors
- Thermal energy is abundantly available, and especially low-grade heat is often wasted in industrial processes as a by-product. Tapping into this vast energy reservoir with cost-attractive technologies may become a key element for the transition to an energy-sustainable economy and society. We propose a novel heat-to-current converter which is based on the temperature dependence of the cell voltage of charged supercapacitors. Using a commercially available supercapacitor, we observed a thermal cell-voltage rise of around 0.6 mV K-1 over a temperature window of 0 [degree]C to 65 [degree]C. Within our theoretical model, this can be used to operate a Stirling-like charge-voltage cycle whose efficiency is competitive to the most-efficient thermoelectric (Seebeck) engines. Our proposed heat-to-current converter is built from cheap materials, contains no moving parts, and could operate with a plethora of electrolytes which can be chosen for optimal performance at specific working temperatures. Therefore, this heat-to-current converter is interesting for small-scale, domestic, and industrial applications.
Document Type: | Article |
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Author: | Andreas Härtel, Mathijs Janssen, Daniel Weingarth, Volker PresserORCiD, René van Roij |
URN: | urn:nbn:de:bsz:291:415-3569 |
DOI: | https://doi.org/10.1039/c5ee01192b |
ISSN: | 1754-5692 |
Parent Title (English): | Energy & Environmental Science |
Volume: | 8 |
Issue: | 8 |
First Page: | 2396 |
Last Page: | 2401 |
Language: | English |
Year of first Publication: | 2015 |
Date of final exam: | 2015/07/13 |
Release Date: | 2022/11/18 |
Impact: | 25.427 (2015) |
Funding Information: | German Federal Ministry for Research and Education (BMBF) in support of the nanoEES3D project (award number 03EK3013). |
Scientific Units: | Energy Materials |
Open Access: | Open Access |
Signature: | INM 2015/59 |
Licence (German): | Creative Commons - CC BY - Namensnennung 4.0 International |