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One-step synthesis of nanocrystalline transition metal oxides on thin sheets of disordered graphitic carbon by oxidation of MXenes

  • Herein we show that heating 2D Ti 3 C 2 in air resulted in TiO 2 nanocrystals on thin sheets of disordered graphitic carbon structure that can handle extremely high cycling rates when tested as anodes in lithium ion batteries. Oxidation of 2D Ti 3 C 2 in either CO 2 or pressurized water also resulted in TiO 2 /C hybrid structure. Similarly, other hybrids can be produced, as we show here for Nb 2 O 5 /C from 2D Nb 2 C.

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Metadaten
Document Type:Article
Author:Michael NaguibORCiD, Olha Mashtalir, Maria R. Lukatskaya, Boris DyatkinORCiD, Chuanfang Zhang, Volker PresserORCiD, Yury GogotsiORCiD, Michel W. Barsoum
URN:urn:nbn:de:bsz:291:415-4098
DOI:https://doi.org/10.1039/C4CC01646G
ISSN:1359-7345
Parent Title (English):Chemical Communications
Volume:50
First Page:7420
Last Page:7423
Language:English
Year of first Publication:2014
Release Date:2022/11/18
Impact:06.834 (2014)
Funding Information:National Science Foundation (DMR-1310245); NSF (CNS-0960061); German Federal Ministry nanoEES3D project (03EK3013); Chinese Scholarship Council (CSC).
Scientific Units:Energy Materials
Open Access:Open Access
Signature:INM 2014/045
Licence (German):License LogoCreative Commons - CC BY - Namensnennung 4.0 International