Tris(tetrahydrofuran- κ O)tris[tris(thiophen-2-yl)methanolato- κ O]terbium(III) tetrahydrofuran monosolvate
- In the mononuclear title compound, [Tb(C 13 H 9 OS 3 ) 3 -(C 4 H 8 O) 3 ]·C 4 H 8 O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octahedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.
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| Document Type: | Article |
|---|---|
| Author: | Michael Veith, Celine Belot, Volker HuchORCiD |
| URN: | urn:nbn:de:bsz:291:415-4799 |
| DOI: | https://doi.org/10.1107/S160053681104623X |
| ISSN: | 1600-5368 |
| Parent Title (English): | Acta Crystallographica E |
| Title Parent (short): | Acta Crystallogr E |
| Volume: | E67 |
| Issue: | 12 |
| Pagenumber: | m1712 |
| Language: | English |
| Year of first Publication: | 2011 |
| Release Date: | 2022/11/18 |
| Tag: | R = 0.035; T = 132 K; data-to-parameter ratio = 23.9; disorder in main residue; mean σ(C-C) = 0.006 Å; single-crystal X-ray study; wR = 0.085 |
| Impact: | 00.347 (2011) |
| Funding Information: | DFG in the framework of the SPP1166 (Lanthanoidspezifische Funktionalitäten in Molekül und Material), Saarland University and the Fonds der Chemischen Industrie |
| Open Access: | Open Access |
| Signature: | INM 2011/070 |
| Licence (German): |  Creative Commons - CC BY - Namensnennung 4.0 International |
