Gallium and Indium Alkoxides with Hydride, Cyclopentadienediide and Copper(I) tert-Butoxide as further Components
- Gallium hydride stabilized by the base quinonuclidine reacts with acetone under addition of the Ga-H function to the carbon–oxygen double bond yielding (HGa)5(OiPr)8O (1) as isolable compound. (HGa)5(OiPr)8O may be formally split in to four entities of HGa(OiPr)2 and one entity HGaO. The inner atomic skeleton of 1 is a novel Ga5O9 heterocluster with gallium atoms occupying the corners of a distorted trigonal bi-pyramid, an oxygen atom in the center and the remaining alcoholate oxygen atoms bridging eight of the nine edges of the bi-pyramid (X-ray diffraction analysis). Potassium indium alkoxide KIn(OtBu)4 has been used to synthesize several new compounds like In4(OtBu)8(C5H4)2 (2), (py)2CuIn(OtBu)4 (3), and [CuIn(OtBu)4]2 (4) by reaction with TiCl2cp2 (2) and CuCl (3, 4). All compounds were characterized by spectroscopic means and by X-ray structure analyses revealing novel polycyclic structures.
| Document Type: | Article |
|---|---|
| Author: | Michael Veith, Daniela Summa, Uwe Annel, Volker HuchORCiD |
| URN: | urn:nbn:de:bsz:291:415-4824 |
| DOI: | https://doi.org/10.1002/zaac.201900240 |
| ISSN: | 0044-2313 |
| Parent Title (English): | Zeitschrift für anorganische und allgemeine Chemie |
| Volume: | 645 |
| Issue: | 22 |
| First Page: | 1272 |
| Last Page: | 1278 |
| Language: | English |
| Year of first Publication: | 2019 |
| Release Date: | 2022/11/18 |
| Impact: | 01.240 (2019) |
| Funding Information: | Fonds der Chemischen Industrie |
| Open Access: | Open Access |
| Signature: | INM 2019/086 |
| Licence (German): |  Creative Commons - CC BY - Namensnennung 4.0 International |
