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Phase diagram studies for the growth of (Mg,Zr):SrGa12O19 crystals

  • By differential thermal analysis, a concentration field suitable for the growth of Zr, Mg co-doped strontium hexagallate crystals was observed that corresponds well with known experimental results. It was shown that the melting point of doped crystal is ca. 60 K higher than that of undoped crystals. This higher melting points indicate hexagallate phase stabilization by Zr, Mg co-doping and increase the growth window of (Mg,Zr):SrGa12O19, compared to undoped SrGa12O19 that grows from SrO–Ga2O3 melts.

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Document Type:Article
Author:Detlef KlimmORCiD, Bartosz SzczefanowiczORCiD, Nora WolffORCiD, Matthias BickermannORCiD
Parent Title (English):Journal of Thermal Analysis and Calorimetry
First Page:7133
Last Page:7139
Date of Publication (online):2021/09/12
Year of first Publication:2022
Release Date:2022/08/03
Tag:Crystal growth; Hexaferrite structure; Metastability; Phase diagram; Thermal analysis
Impact:04.755 (2021)
Groups:Interaktive Oberflächen
DDC classes:500 Naturwissenschaften und Mathematik / 540 Chemie
Open Access:Open Access
Signature:INM 2022/007
Licence (German):License LogoCreative Commons - CC BY - Namensnennung 4.0 International